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Chemicals, plastics and rubber industries

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Abstracts » Chemicals, plastics and rubber industries

Evidence for Fenton photoassisted processed mediated by encapsulated Fe ions at biocompatible pH values

Article Abstract:

Fenton photoassisted processes were examined.

Author: Fernandez, J., Kiwi, J., Dhananjeyan, M.R., Senuma, Y., Hilborn, J.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Biodegradation, Aromatic compounds

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Abatement of an azo dye on structured C-Nafion/Fe-ion surfaces by photo-Fenton reactions leading to carboxylate intermediates with a remarkable biodegradability increase of the treated solution

Article Abstract:

C-Nafion/Fe-ion fabric is presented as a composite material being applied for the first time as a stable immobilized catalyst decomposing Orange II by Fenton photo-assisted reactions. A detailed characterization of the surface parameters of the C-Nafion/Fe-ion fabric is worked out through X-ray Photoelectron Spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and BET techniques.

Author: Kiwi, J., Parra, S., Guasaquillo, I., Enea, O., Mielczarski, E., Mielczarki, J., Albers, P., Kiwi-Minsker, L.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
Science & research, Usage, Optical properties, X-ray spectroscopy, Iron compounds, Chemistry, Physical and theoretical, Physical chemistry

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Discoloration of azo-dyes at biocompatible pH-values through an Fe-histidine complex immobilized on nafion via Fenton-like processes

Article Abstract:

The pH range of Fe-loaded nation in the orange II discoloration is extended up to 10.2 through the development of an innovative catalyst of Fe/histidine prepared in sity on the Nafion. This avoids the expensive initial pH adjustment in Fenton homogenous reactions. The Fe/histidine/nafion membrane is observed to be resistant to oxidative radical attack by the radicals generated in solutions up to 30 mm H2O2 at acid, neutral, and basic pH values (10.2).

Author: Kiwi, J., Parra, S., Albers, P., Nadtotechenko, V.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
Cyclic crudes and intermediates, Azoic Dyes & Components, Synthetic Organic Dye and Pigment Manufacturing, Iron, Iron (Metal), Histidine, Azo dyes, Chemical properties

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Subjects list: Research
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