Aged titania nanoparticles: The simultaneous control of local and long-range properties

Article Abstract:

A procedure that combines hydrothermal treatments of variable time length performed in mild conditions, with a sol-gel route to obtain the titanium oxide hydrous precursor is presented. The combination of aging steps, performed in mild conditions with the opportune selection of the sol-gel parameters, has led to ordered anatase nanocrystalline powders of 6-8nm with large surface area and small interparticle mesopores.

Author: Anedda, Alberto, Cappelletti, Giuseppe, Ricci, Carlo, Ardizzone, Silvia, Parola, Claudia
Nanotechnology, Titanium compounds, Hydrothermal fluids

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A comparative study on electrochemical macromachining of n-GaAs and p-Si by using confined etchant layer technique

Article Abstract:

A study demonstrates that 3-D micromachining by indirect electrochemical etching of n-GaAs and p-Si can be accomplished using the confined etchant layer technique (CELT) with appropriate etching solutions. Results indicate that the success of this process depends mainly on the concentration of l-cystine to [Br.sup.-] in the etching solution.

Author: Li Zhang, Xin Z. Ma, Mi X. Lin, Lin, Yu, Guo H. Cao, Jing Tang, Zhao W. Tian
Arsenic & Compounds, Gallium Compounds, Electric properties, Arsenic compounds, Electrochemistry

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Structural and spectroscopic investigation of blue, vanadium-doped ZrSiO(sub 4) pigments prepared by a Sol-Gel route

Article Abstract:

A sol-gel reaction starting from silicon and zirconium alkoxides in water-ethanol mixtures was employed to obtain vanadium-doped zirconium silicate powders (zircon) were performed. The study revealed that addition of NaF apart from promoting the blue color and the zircon structures causes the localization of V in sites with lower symmetry.

Author: Cappelletti, Giuseppe, Ardizzone, Silvia, Scime, Fabio, Fermo, Paola, Scavini, Marco
Zirconium Compounds, Analysis, Spectrum analysis, Spectroscopy

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Subjects list: Research, Chemical properties, Silicon compounds
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