Electric-field -induced reorientation of a ferroeletric liquid crystal molecule without a carboxylate group near the stereocenter studied by time resolved infrared spectroscopy combined with normalized sample-sample two- dimensional correlation spectroscopy
Article Abstract:
The electric-field-induced switching of FCL-2 without carboxylate group near the stereocenter is explored by using polarised time-resolved IR spectroscopy combined with normalized sample-sample 2D correlation spectroscopy. Results show that the reorientation track of the core in the positive half-period is different from that in the negative half-period, while the reorientation track of the C=O dipole moment and the alkyl chains are very much alike between the positive and negative half-periods.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
User Contributions:
Comment about this article or add new information about this topic:
Thermal property of an octadecyldimethylamine oxide multilayer Langmuir-Blodgett film studied by an expanded model for quantitative molecular orientation analysis with infrared reflection-absorption spectrometry
Article Abstract:
Results indicate that analysis of the thermal property of octadecyldimethylamine oxide (C(sub)18DAO) multilayer Langmuir-blodgett film exhibits great disorder in the first layer of the film between 50 and 60 C. This differential thermal property between first and the rest of the layers suggests that the headgroup of C(sub)18DAO possesses strong dipole activity.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
User Contributions:
Comment about this article or add new information about this topic:
In situ examination of the structure of model reversed-phase chromatographic interfaces by sum-frequency generation
Article Abstract:
Sum-frequency generation (SFG) spectroscopy was used to examine model reversed-phase chromatographic interfacial systems. Solvent microheterogeneity had a huge effect on alkyl chain order.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Association of methanol and water in ionic liquids elucidated by infrared spectroscopy using two-dimensional correlation and multivariate curve resolution
- Abstracts: Surface-induced J aggregation of pseudoisocyanine dye at a glass/solution interface studied by total-internal-reflection fluorescence spectroscopy
- Abstracts: Characterization of Mo-P-alumina sol-gel catalysts by solid-state 31P and 27Al magic-angle spinning nuclear magnetic resonance and two-dimensional 27Al multiple-quantum magic-angle spinning nuclear magnetic resonance
- Abstracts: Structural characterization of supported platinum carbonyl clusters by X-ray absorption spectroscopy. Isotopic exchange of CO adsorbed on Pt(111)
- Abstracts: g-Anisotropy of the [S.sub.2]-state manganese cluster in single crystals of cyanobacterial photosystem II studied by W-band electron paramagnetic resonance spectroscopy