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Electronic structure of the nucleobases

Article Abstract:

A comparison is made between the experimental and calculated soft X-ray spectra of DNA's nucleobases, adenine, guanine, cytosine, and thymine using X-ray absorption spectroscopy and soft X-ray emission spectroscopy. The experimental and theoretical results for the four nucleobases show that each cell has a unique partial density of states for the carbon, nitrogen, and oxygen sites.

Guanine, Optical properties, Electron configuration

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Resonance Raman and UV-Vis spectroscopic characterization of FADH in the complex of photolyase with UV-damaged DNA

Article Abstract:

Resonance Raman and UV-vis spectroscopy is used to investigate the interactions between the active site in unmanipulated photolyase and UV-damaged DNA. The substrate binding of unmanipulated Escherichia coli photolyase induces changes in both the resonance Raman and the absorption spectrum of flavin adenine dinucleotide (FADH.).

Usage, Spectrum analysis, Spectroscopy, DNA-ligand interactions, DNA binding

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Leading RNA tertiary interactions: Structures, energies, and water insertion of A-minor and P-interactions

Article Abstract:

The quantum chemical study results from key tertiary interaction patterns in RNA reveal A-minor interactions to be formed by adenine interacting through its sugar edge with a WC base pair from a canonical double helix while the P-interaction was found to bring together a G/U wobble base pair and a GC WC base pair.

RNA, Genetic research

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