Electrostatic interactions of a neutral dipolar solute with a fused salt: A new model for solvation in ionic liquids
Article Abstract:
A model for solute-solvent electrostatic interactions in ionic liquid is described which provides screening of the solute electric field without polarization of the medium, solving a possible contradiction between the weakness of solute-solvent interactions and the behavior of a conductive system. The model forecasts the nature of the solute-solvent interactions in ionic liquids and it is consistent with the empirical data on testing.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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Dinitramide ion: Robust molecular charge topology accompanies an enhanced dipole moment in its ammonium salt
Article Abstract:
The electron density, rho(r), of crystalline ammonium dinitramide (ADN) was determined from low-temperature X-ray diffraction data and electronic structure calculations. It is concluded that in salts, the range of the nitro group rotations remains in a region where the formal charge on the central nitrogen can be effectively delocalized.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2003
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On the determination of partial molar polarizations and dipole moments of solutes from multicomponent solutions alone: experimental and model development using deutero-labeled organic compounds
Article Abstract:
A model quaternary system consisting of three deuterated solutes are studied. Three different numerical approaches are used to determine the individual limiting solute molar polarizations from the multicomponent solutions.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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