Improved quasi-chemical equation of state based on energy and density fluctuations in the small system grand canonical ensemble
Article Abstract:
The theory and model approximations for a simple, single-component fluid represented by a body-centered cubic lattice gas with nearest-neighbor attractions (bcc-LG) are reported. The resulting model is found to give significantly improved predictions of the effects of temperature on local density fluctuations compared to the case, in which such correlations are neglected, with results in semiquantitative agreement with those from molecular simulations.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
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Effects of the polarizability and packing density of transparent oxide films on water vapor permeation
Article Abstract:
The oxide's polarizability and the packing density of the oxide films control water vapor permeation through the oxide films. Water chemically interacts with the oxide films and forms a multilayer consisting of the OH groups and the continuing absorbed water vapor on the surface and the pore of the oxide films.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
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