Ion-pair and solvent relaxation processes in aqueous Na2SO4 solutions

Article Abstract:

A study was conducted on the association of sodium and sulfate ions in concentrated aqueous solutions in connection with a variety of chemical systems. A thorough dielectric resonance spectroscopic investigation of the Na2SO4/H2O system was undertaken and its results are discussed. This system is also a useful staring point for a systematic study of weak ion association in aqueous electrolytes because of the availability of the appropriate reference data.

Author: Hefter, Glenn, Buchner, Richard, Capewell, Stephen G., May, Peter M.
Ion exchange, Molecular association, Solution (Chemistry), Solutions (Chemistry), Chemical systems, Sodium sulfates, Sodium sulfate

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Complexity in 'simpleE electrolyte solutions: ion pairing in MgSO4 (aq)

Article Abstract:

Detailed analysis of dielectric relaxation spectroscopy shows the simultaneous presence of double solvent separated (2 SIP), solvent-shares (SIP) and contact (CIP) ion pairs. The implications of the thermodynamic behavior of higher-valent electrolytes for quantitative models are discussed.

Author: Hefter, Glenn, Buchner, Richard, Chen, Ting
Science & research, Spectrum analysis, Spectroscopy, Chemistry, Analytic, Electrolyte solutions, Dielectric relaxation, Quantitative chemical analysis

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Ion association and hydration in aqueous solutions of LiCl and [Li.sub.2]S[O.sub.4] by dielectric spectroscopy

Article Abstract:

The study results from analysis of dielectric relaxation spectra of aqueous solutions of LiCl and [Li.sub.2]S[O.sub.4] showed to two lithium salts to share many similar characteristics.

Author: Hefter, Glenn, Buchner, Richard, Wachter, Wolfgang, Fernandez, Sarka
All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Lithium Compounds, Analysis, Spectra, Aqueous solution reactions, Chemical properties, Hydration (Chemistry)

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Subjects list: Research
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