Lability of a mixture of metal complexes under steady-state planar diffusion in a finite domain
Article Abstract:
A methodology to determine the effect of a ligand mixture on the contribution of the complexes to the metal flux in systems under diffusion-limited conditions in a planar finite domain for any value of the association/dissociation rate constants is developed. The results have shown that the mixture effect can lead to an increase or decrease of the degree of lability of a complex in a mixture and can have a major impact on the metal flux, especially under conditions that render both complexes partially labile.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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Transport properties in ionic liquids and ionic liquid mixtures: The challenges of NMR pulsed field gradient diffusion measurement
Article Abstract:
The data results from studies conducted shows that the pulsed gradient spin echo (PGSE) method suffers from intrinsic internal gradients and could produce apparent diffusion coefficients which vary by as much as 20% for different [super 1]H nuclei within a given molecule.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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Mass transport model for semiconductor nanowire growth
Article Abstract:
A mass transport model based on surface diffusion for metal-particle-assisted nanowire growth is presented. The results demonstrate that the Gibbs-Thomson effect can be neglected for III/V nanowires grown at conventional temperatures and pressures.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
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