Local structure and near-infrared emission features of neodymium-based amine functionalized organic/inorganic hybrids
Article Abstract:
The sol-gel derived di-urea and di-urethane cross-linked poly(oxyethylene)/ siloxane hybrids (di-ureasils and di-urethanesils, respectively) doped with neodymium triflate (Nd(CF(sub 3)SO(sub 3)(sub 3) were examined. The conclusion derived from the study is that hydrogen-bonded associations formed throughout the materials play a major role in the hybrids nanostructure and photoluminescence properties.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
User Contributions:
Comment about this article or add new information about this topic:
Coordination of Eu(super 3+) ions in siliceous nanohybrids containing short polyether chains and bridging urea cross-links
Article Abstract:
The local environment of the Eu(super 3+) ions in luminescent sol-gel derived materials di-ureasils is investigated with the use of infrared and photoluminescence spectroscopies. The results showed that the coordination of the cations in the di-ureasils depends both on the guest salt concntration and on the length of the polymer chains incorporated.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
User Contributions:
Comment about this article or add new information about this topic:
Eu(super 3+) coordination in an organic/inorganic hybrid matrix with methyl end-capped short polyether chains
Article Abstract:
The anionic and cationic local environments in mono-urethanesils doped with europium triflate (Eu(CF3SO3)3) are examined. It was carried out with the help of Fourier Transform mid-infrared (FT-IR), Fourier Transform Raman (FT-Raman) and photoluminescence spectroscopies and Two-Dimensional (2D) Correlation Spectroscopic Analysis.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Photochemistry of ruthenium trisbipyridine functionalized on gold nanoparticles. Long-Lived Photoinduced Charge Separation in Ru(Bpy)(sub 3)(super 2+)/Viologen System at Nafion Membrane -Solution Interface
- Abstracts: Full and modulated chemical gating of individual carbon nanotubes by organic amine compounds. Microscopic description of elementary growth processes and classification of structural defects in pentacene thin films
- Abstracts: Structure and dynamics of a Bronsted acid site in a zeolite: ab initio study of hydrogen sodalite. On the role of Ti(IV) as a Lewis acid in the chemistry of titanium zeolites: Formation, structure, reactivity, and aging of Ti-peroxo oxidizing intermediates: A first principles study
- Abstracts: Effect of the structure of cobalt nanocrystal organization on the collective magnetic properties. Cobalt(III) effect on (super 27)Ai NMR chemical shifts in LiAl(sub x)Co(sub 1-x)O(sub 2)