Preparation and spectroscopic characterization of [Pt(en)2I2][Pt(CN4): a new quasi-one-dimensional mixed valence chain material in a completely ordered lattice

Article Abstract:

The synthesis, structure and characterization of a new metal chain compound, [Pt(en)2I2][Pt(CN)4], where en=ethylenediamine, is presented. Analysis shows the new compound is quasi-one-dimensional in a completely ordered lattice.

Coordination compounds, Metal complexes (Chemistry)

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Phase behavior of a structurally constrained organic-inorganic crystal: temperature-dependent infrared spectroscopy of silver n-dodecanethiolate

Article Abstract:

Issues concerning the solid-solid transitions between 25 degrees C and 250 degrees C of silver n-dodecanethiolate by use of temperature-dependent Fourier transform infrared spectroscopy are presented.

Usage, Condensed matter, Chemical reaction, Rate of, Chemical kinetics, Fourier transform infrared spectroscopy, Silver compounds

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Nonequilibrium pattern formation in Langmuir-phase assisted assembly of alkylsiloxane monolayers

Article Abstract:

An investigation is described involving the deposit of prepolymerized n-octadecyltrichlorosilane monolayers onto oxidized silicon substrates from precursor Langmuir monolayers in two-dimensional liquid expanded, liquid condensed or mixed states at a variety of pulling rates.

Morphology (Biology), Morphology, Surface chemistry

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