Sticking probabilities in adsorption of alkanethiols from liquid ethanol solution onto goldR

Article Abstract:

The sticking probability, the rate of adsorption per molecular collision with the surface, is the most fundamental and powerful way to express adsorption rate constants, yet its accurate use has been restricted almost exclusively to adsorption from the gas phase. This concept is extended to transient rate measurements of adsorption from liquid solutions, and applies it to clarify the dynamics of alkanethiol adsorption on gold.

Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), All Other Basic Organic Chemical Manufacturing, Industrial organic chemicals, not elsewhere classified, Industrial Organic Chemicals, Gold, Ethanol, Ethyl Alcohol Manufacturing, Mercaptans, Alcohol, Alkanes, Thiols, Chemical properties, Alcohol, Denatured

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Comment on "synthesis of fully dehydrated fully Zn(super 2+)-exchanged zeolite Y and its crystal structure determined by pulsed-neutron diffraction". Cationic zinc clusters formally containing Zn(I) in the sodalite cavities of zeolite Y (FAU)

Article Abstract:

Electron-microprobe method is carried out using a CAM-ECA SX50 instrument for the analysis of Zn-Y (FAU). It shows that the zinc ions are present per unit cell, substantially more than the 27.5 Zn(super 2+) ions that would be needed to balance the 55- anionic charge of the zeolite framework.

All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Zeolites, Secondary nonferrous metals, Crystals, Crystal structure, Zinc, Zinc (Metal), Structure

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