Study on synthesis and electrochemical properties of a novel ferrocene-based compound and its application in anion recognition

Article Abstract:

A novel ester-ferrocene compound 2-Fc with a special structure is synthesized through the ring-opening-addition reaction of ferrocene carbonate acid and epoxy rosin and its cyclic voltammetry (CV) behavior in different organic solutions are determined. The results have shown that solvents with different polarities have different impact on charge transport and the stability of the positively charged ferrocenium 2-Fc, thus affecting the CV behaviors of 2-Fc.

Analysis, Metallocenes, Chemical synthesis, Voltammetry, Anions, Structure

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Novel thermoresponsive and pH-responsive aggregates form self-assembly of triblock copolymer PSMA-b-PNIPAAm-b-PSMA

Article Abstract:

The carboxyl-terminated trithiocarbonates were subjected to reversible addition-fragmentation chain transfer (RAFT) polymerization to obtain a series of triblock copolymers of poly (steryl methacrylate)-b-poly (N-isopropylacrylamide)-b-poly-stearyl methacrylate)( PSMA-b-PNIPAAm-b-PSMA) having different molecular weights. The polymers were found to be thermoresponsive and pH-responsive.

Acrylamides, Usage, Thermal properties, Fourier transform infrared spectroscopy, Block copolymers, Acrylamide, Methacrylates, Report

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Study on the synthesis of poly(diglycidyl amleate-co-stearyl methacrylate) and morphology conversion of their self-assembly systems

Article Abstract:

A novel polymer of poly(diglycidyl maleate-co-stearyl methacrylate) (P(DGMA-co-SMA)) was synthesized by reaction between poly(maleic anhydride-co-stearyl methacrylate) (P(MA-co-SMA)) and epichlorohydrin. The self-assembly behavior of the resultant copolymer was investigated.

Science & research, Epichlorohydrin, Research, Anhydrides, Copolymers

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