Quenching of IR luminescence of erbium, neodymium, and ytterbium beta-diketonate complexes by ligand C-H and C-D bonds

Article Abstract:

A detailed study of the role of CH and CD quenching on the luminescence of [Er.sup.3+], [Nd.sup3+] and [Yb.sup.3+] ions in the Cs[Ln[(HFA).sub.4]] system is presented. The results show that for [Er.sup.3+] ions the rapid luminescence quenching is strongly dependent on the immediate local environment with only a second effect due to more distant CH bonds.

Author: Motevalli, Majid, Wyatt, Peter B., Tan, Rendy H.C.
Neodymium & Compounds, Analysis, Luminescence, Neodymium, Erbium

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Energetics and thermodynamic stability of the mixed valence ytterbium germanides

Article Abstract:

The thermodynamic stability of the Yb germanides, described as intermediate valence compounds, is analyzed. The high-temperature decomposition reaction of YbGe intermediate phases is studied by Knudsen effusion mass (KEMS) and Knudsen effusion weight loss (KEWL) techniques.

Author: Baldcucci, G., Brutti, B., Ciccioli, A., Gigli, A., Palenzona, A., Pani, M.
Science & research, Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Ytterbium & Compounds, Germanium, Research, Thermal properties, Thermodynamics, Ytterbium, Report

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Subjects list: Electric properties
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