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Gas-phase interaction of thiophene with the T[i.sub.8][C.sub.12][.sup.+] and T[i.sub.8][C.sub.12]met-car clusters

Article Abstract:

The reactivity of the T[i.sub.8][C.sub.12][.sup.+] met-cat cation toward thiophene was investigated using density functional theory (DFT) and mass selective ion chemistry. The binding behavior for subsequent addition of thiophene molecules to the neutral met-car was presented and compared to that of the cation.

Usage, Observations, Phase transformations (Statistical physics), Phase transitions (Physics), Density functionals, Density functional theory, Titanium compounds, Thiophene

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MCM-41 supported Cu-Mn catalysts for catalytic oxidation of toluene at low temperatures

Article Abstract:

Cu-Mn containing mesoporous and microporous catalysts are used for the complete oxidation of toluene. The bimetallic Cu-Mn-MCM-41 supported catalysts show higher oxidation activity than either single metal catalyst that is Cu-MCM-41 and Mn-MCM-41.

All Other Basic Inorganic Chemical Manufacturing, Petrochemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Toluene, Manganese Compounds, Analysis, Oxidation-reduction reaction, Oxidation-reduction reactions, Porous materials, Copper compounds

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