Magnetic TTF-based charge-transfer complexes
Article Abstract:
TTF-type organic charge-transfer complexes exhibit a variety of electronic phases, such as charge density wave states, spin density wave states, mott insulators, charge ordering states, metals, superconductors and so on. Hybrid systems of charge-transfer complexes obtained based on donors and anions can easily combine functions of the constituent building blocks, leading to multifunctional materials.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
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Organic metals and superconductors based on BETS (BETS = Bis (ethylenedithio) tetraselenafulvalene)
Article Abstract:
When using BETS molecules and typical magnetic anions such as FeCl4 (super -) and FeBr4 (super -), various types of new magnetic conductors including the first antiferromagnetic and metamagnetic superconductors are discovered. The conductors exhibiting unprecedented superconductor-insulator transitions and field-induced organic superconductors are disclosed.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
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Electron spin resonance:A major probe for molecular conductors
Article Abstract:
Selected results of the research on molecular conductors are chosen to illustrate the relevance of the ESR technique in this field. Molecular conductors display a wide variety of electronic ground states including paramagnetic, ferromagnetic, antiferromagnetic, Spin-Peierls, Peierls and super-conducting ground states.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2004
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- Abstracts: New trends in the synthesis of pi-electron donors for molecular conductors and superconductors. Synthesis and reactivity of Ru-, Os-, Rh-, and Ir-halide-sulfoxide complexes
- Abstracts: Toward systematic understanding of diversity of electronic properties in low-dimensional molecular solids. Conjugated polymers and aromaticity
- Abstracts: Boron reagents in process chemistry: Excellent tools for selective reductions. Single-component molecular metals with extended-TTF dithiolate ligands