Templated photochemistry: Toward catalysts enhancing the efficiency and selectivity of photoreactions in homogeneous solutions
Article Abstract:
The templated photochemical reactions in a homogeneous solution, which are initiated or mediated by light, are reviewed. The findings suggest that shielding of prochiral faces, topochemical reaction control, templating, and aggregate or inclusion complex formation are strategies responsible for enhancing and controlling reaction efficiency regio- or stereoselectivity.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2006
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Advances in homogeneous and heterogeneous catalytic asymmetric epoxidation
Article Abstract:
The progress of homogeneous and heterogeneous catalytic chiral epoxidation is summarized to grant a convenient and wide vision for the understanding of peers working in the area of asymmetric catalysis. In several systems, there is still a large space to improve the enantioselectivity and chemoselectivity of the asymmetric epoxidations.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2005
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