Thermodynamic scales for sulfur atom transfer and oxo-for-sulfido exchange reactions
Article Abstract:
An attempt is made to identify thermodynamic reactivity scale of new molecular sulfides including both organic and inorganic to determine their relative strengths of potential donors and acceptors atom. Some of the chief reagents studied include hexasulfur ([S.sub.6]), dialkyl dithiiranes, sulfur diimides, bis(tri-n-butylstannyl)sulfide, and 5-aryloxy-1,2,3,4-thiatriazoles and oxo-for-sulfido exchange reagents such as Si[S.sub.2], Ph3SiSH.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2006
User Contributions:
Comment about this article or add new information about this topic:
Chiral sulfur ligands for asymmetric catalysis
Article Abstract:
The article discusses the synthesis and properties of various chiral sulfur ligands, which are commonly employed for asymmetric catalysis. The sulfur ligands are found to be much more efficient than any other metal ligand.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2007
User Contributions:
Comment about this article or add new information about this topic:
Nitrogen-containing ligands for asymmetric homogeneous and heterogeneous catalysis
Article Abstract:
The most recent results regarding the use of nitrogen-containing ligands for asymmetric catalysis are presented. The results are categorized according to the type of catalytic reaction involved.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2000
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Electrostatic basis for enzyme catalysis. Mechanisms and free energies of enzymatic reactions. Advances in time-resolved approaches to characterize the dynamical nature of enzymatic catalysis
- Abstracts: Membranes for hydrogen separation. [NiFe] and [FeFe] hydrogenases studied by advanced magnetic resonance techniques
- Abstracts: Complex hydrides for hydrogen storage. Thermochemical cycles for high-temperature solar hydrogen production. Hydrogen production by molecular photocatalysis