Transition-metal systems in biochemistry studied by high-accuracy quantum chemical methods
Article Abstract:
A review of research in the field of accurate quantum chemical treatments of systems containing transition metals is presented. It was found that there are at least two clear differences in the applications on biochemical systems in comparison with other transition-metal complexes. The overall chemistry in which the biochemical complexes are involved is a lot more complicated than in a conventional catalytical cycle of a laboratory procedure.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2000
User Contributions:
Comment about this article or add new information about this topic:
Theoretical studies of some transition-metal-mediated reactions of industrial and synthetic importance
Article Abstract:
Examples are used to indicate how quantum chemistry has been applied to address real problems found in coordination chemistry for which experimental chemistry alone could not produce an answer. It is suggested that theoretical studies have greatly improved understanding of a wide range of transition-metal-mediated reactions.
Publication Name: Chemical Reviews
Subject: Chemistry
ISSN: 0009-2665
Year: 2000
User Contributions:
Comment about this article or add new information about this topic:
Density functional theory of biologically relevant metal centers
Article Abstract:
This article applies density functional theory to biologically important large metal enzyme complexes in the elucidation of mechanism, structure, and modeling. Metalloenzymes comprising methane monooxygenase, photosystem II complex, nitrogenase, the copper dimer active site in tyrosinase, and hemocyanin are described.
Publication Name: Annual Review of Physical Chemistry
Subject: Chemistry
ISSN: 0066-426X
Year: 1999
User Contributions:
Comment about this article or add new information about this topic:
- Abstracts: Structural aspects of fullerene chemistry--A journey through fullerene chirality. Tetrathiafulvalence cyclophanes and cage molecules
- Abstracts: Early events in protein folding explored by rapid mixing methods. Conformation of the backbone in unfolded proteins
- Abstracts: Heterogeneous chemistry of carbon aerosols. Stochastic simulation of chemical kinetics. Raman crystallography and other biochemical applications of Raman microscopy
- Abstracts: Microphysics and heterogeneous chemistry of polar stratospheric clouds. Chemistry and microphysics of polar stratospheric clouds and cirrus clouds
- Abstracts: Metal-assisted cycloaddition reactions in organotransition metal chemistry. The chemistry of highly strained oligospirocyclopropane systems