vic-Diacrylic ester porphyrins as starting materials for monobenzoporphyrin and opp-dibenzoporphyrin syntheses
Article Abstract:
Synthesis of a bis(vic-diacrylic ester) porphyrin has been carried out using the 3+1 methodology. A 2-step procedure was used to convert the bis(vic-diacrylic ester) porphyrin and vic-diacrylic ester porphyrin to the opp-dibenzoporphyrin and the monobenzoporphyrin, respectively. The compounds have been characterized by UV-visible and H NMR spectroscopies. Benzoporphyrins are interesting chromophores that may be applied in time as photosensitizers for photodynamic therapies. This is especially true of the lower analog mono- and dibenzo- compounds in the class. A new generation of photosensitizers is needed for development of a new therapy.
Publication Name: Canadian Journal of Chemistry
Subject: Chemistry
ISSN: 0008-4042
Year: 1998
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Syntheses and UV-vis spectroscopic properties of new lipophilic tert-butyl- and 1-adamantyl substitutes, negatively solvatochromic pyridinium N-phenolate betaine dyes
Article Abstract:
To get zwitterionic dyes more soluble in nonpolar solvents, syntheses and negative solvatochromisms of two new lipophilic pentaphenyl pyridinium N-phenolate betaine dyes substituted with either seven tert-butyl groups or three tert-butyl and two 1-adamantyl groups in the outer phenyl rings have been carried out. Visible ultraviolet (UV-vis) spectroscopic properties have been considered. Standard betaine dye would be an example of a nonpolar solvent.
Publication Name: Canadian Journal of Chemistry
Subject: Chemistry
ISSN: 0008-4042
Year: 1998
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