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Transition state spectroscopy

Article Abstract:

Transition state spectroscopy has been used to experimentally characterize the transition state for inversion in cyclooctatetraene (C8H8). The research represents an important step forward because the reaction of C8H8 is much more complex than that usually accessible to transition state spectroscopy.

Author: Neumark, Daniel M.
Publisher: American Association for the Advancement of Science
Publication Name: Science
Subject: Science and technology
ISSN: 0036-8075
Year: 1996
Usage, Chemical structure, Molecular spectroscopy

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Catching an elusive cation

Article Abstract:

Peter de Rege, John Gladysz and Istvan Horvath have directly observed the formyl cation (HCO+) reaction intermediate in chemical reactions in superacidic media. Their spectroscopic methods are described.

Author: Prakash, G.K. Surya
Publisher: American Association for the Advancement of Science
Publication Name: Science
Subject: Science and technology
ISSN: 0036-8075
Year: 1997
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Subjects list: Research, Chemical reactions
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