A combined solid-state NMR and diffraction study of the structures and acidity of fluorinated aluminas: implications for catalysts

Article Abstract:

The structures of a series of pristine and Zn(super 2+)-impregnated aluminas are investigated following fluorination with HF, by using both solid-state NMR and X-ray powder diffraction methods. It is demonstrated that the structural chemistry of fluorinated aluminas is dependent on the starting material, the presence of transition-metal cations, and the nature of the fluorinating agent.

Nuclear magnetic resonance spectroscopy, Chemistry, Physical and theoretical, Physical chemistry

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A combined solid-state NMR and diffraction study of the structures and acidity of fluorinated aluminas: implications for catalysts

Article Abstract:

The structures of a series of pristine and Zn(super 2+)-impregnated aluminas are investigated following fluorination with HF, by using both solid-state NMR and X-ray powder diffraction methods. It is demonstrated that the structural chemistry of fluorinated aluminas is dependent on the starting material, the presence of transition-metal cations, and the nature of the fluorinating agent.

Electric properties, Nuclear magnetic resonance, Zinc

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