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Chemicals, plastics and rubber industries

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Abstracts » Chemicals, plastics and rubber industries

Absence of phase transitions in the hydrogen bond subsystem of associated fluids

Article Abstract:

Phase transitions in the hydrogen bond subsystem of associating fluids are discussed in the framework of mean-field theory. It is presented that in the simplest case of independent bonds the free energy of the subsystem as a function of the numbers of hydrogen bonds is convex.

Author: Clemendot, S, Hutschka, F., Cerdeirina, Claudio A., Romani, Luis, Carballo, Enrique, Veytsman, Boris A.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Fluid dynamics, Hydrogen bonding

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A comparative study on the reactivity of electrogenerated bromine with cyclohexane in acetonitrile and the room temperature ionic liquid, 1-butyl-3-methylimidazolium Bis[(trifluoromethyl)sulfonyl]imide

Article Abstract:

The reactivity of electrogenerated bromine with cyclohexane is studied on a platinum microelectrode. The reaction mechanism for bromination in acetonitrile is modeled using digital simulation.

Author: Compton, Richard G., Hardacre, Christopher, Allen, Gary D., Buzzeo, Marisa C., Davies, Ieuan G., Villagran, Constanza
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
All Other Basic Organic Chemical Manufacturing, Industrial Organic Chemicals, Cyclic crudes and intermediates, Cyclic Crude and Intermediate Manufacturing, Cyclohexane, Acetonitrile, Electric properties, Bromides, Bromides (Chemistry)

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