An experimental study of the line shape of orbital mediated tunneling bands seen in inelastic electron tunneling spectroscopy

Article Abstract:

Research designed to address the matter of line shape and peak position of orbital mediated tunneling bands in normalized tunnelling intensities versus V plots, broadly identified as inelastic electron tunnelling spectroscopy, is presented. It is show that past assignments of the position of orbital mediated tunneling transitions have a small systematic mistake.

Usage, Tunneling spectroscopy

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Orbital-mediated tunneling, inelastic electron tunneling, and electrochemical potentials for metal phthalocyanine thin films

Article Abstract:

Issues concerning orbital-mediated electron tunneling through occupied and unoccupied orbitals of metal phthalocyanines imbedded in metal-insulator-metal tunnel junctions are discussed. The first oxidation and the first reduction of FePc, MnPc and CoPc in a buried interface are presented.

Research, Thin films

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Spontaneous solution-phase redox deposition of a dense cobalt(II) phthalocyanine monolayer on gold

Article Abstract:

A dense monolayer of cobalt(II) phthalocyanine, CoPc, could be formed on a gold surface by spontaneous redox deposition. The spontaneous surface redox adsorption process represents a novel method for depositing metallorganic complexes, which have been ultimately only physisorbed on gold.

Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Industrial Organic Chemicals, Cyclic Crude and Intermediate Manufacturing, Cobalt, Phthalocyanine, Methods, Oxidation-reduction reaction, Oxidation-reduction reactions, Monomolecular films, Chemical properties

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