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Chemicals, plastics and rubber industries

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Structural transitions and glass formation

Article Abstract:

A study on glass formation by cooling liquids below their melting points investigated the gigahertz-frequency mechanical response of glass-forming liquids using the Brillouin light scattering technique. The experiment studied the complex mechanical modulus of various glass forming systems as a function of temperature especially across the glass transition regime. A two-state model is proposed to interpret the thermo-mechanical behavior of several glass forming liquids in a consistent manner.

Author: Kieffer, J.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
Supercooled liquids

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An increasing correlation length in off-equilibrium glasses

Article Abstract:

A study on the presence of a divergent time scale without a corresponding divergence of the correlation length in glass transition presents the results of a simulation for binary fluids using a Monte Carlo algorithm. It will be shown that an increasing correlation length may be identified below the glass transition point if the off-equilibrium correlation functions are investigated. Experimental methods and results are discussed.

Author: Parisi, Giorgio
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
Case studies, Liquids, Monte Carlo method, Monte Carlo methods

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Subjects list: Research, Amorphous substances, Amorphous materials
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