Chemical reaction of nitric oxides with the 5-IDB defect of the single-walled carbon nanotube

Article Abstract:

The chemical reactivity of the 5-1DB defects are assessed from the analyses of the frontier molecular orbitals (FMOS) and local density of states (LDOS) and the reaction of nitric oxides (NOs) with the 5-1DB defects on the single-walled carbon nanotube (SWCNT) is described. It is indicated that the 5-1DB defects on the SWCNT is chemically reactive and can be used as the active site for the functionalization of SWCNT.

Nitric Oxide, Electric properties, Chemical reactions, Molecular orbitals

---

Photoassisted adsorption of allylamine and 1-butene on H:Si(111) studied by surface vibrational spectroscopies

Article Abstract:

Ultraviolet photoadsorption of allylamine and 1-butene on hydrogen terminated Si(111) was performed by delivery of the reactant gases in an ultrahigh-vacuum (UHV) environment. The N-H bonds in allylamine were evidenced to survive over the photoadsorption process by vibrational analysis and by the reaction with ketene.

Cyclic Crude and Intermediate Manufacturing, Butylenes, Butylene, Chemical properties, Allylic compounds

---

FTIR and reaction kinetics studies of the Hydrodehalogenation of CF2Br2, CH2Br2, and CDBr2 over a Pd/gamma-Al2O3 catalyst

Article Abstract:

The hydrodehalogenation of CF2Br2, CH2Br2, and CDBr2 catalyzed by Pd/gamma-Al2O3 catalyst was investigated by a combination of FTIR and chemical reaction studies. Compared to :CH2 carbenes, the :CF2 species are unstable at room temperature on the Pd surface and tend to decompose in the absence of coadsorbed H atoms.

Fourier transform infrared spectroscopy, Halogenation

Similar abstracts:

• Abstracts: Conformational selectivity of peptides for single-walled carbon nanotubes. pH-dependent stability of decalysine alpha-helix studied by explicit-solvent molecular dynamics simulations at constant pH
• Abstracts: Dynamics of C60 encapsulation into single-wall carbon nanotubes. Microstructure and growth model of periodic spindle-unit BN nanotubes by nitriding Fe-B nanoparticles with nitrogen/ammonia mixture
• Abstracts: Adsorption of spillover hydrogen atoms on single-wall carbon nanotubes. A statistical rate theory approach to kinetics of dissociative gas adsorption on solids
• Abstracts: Improved quasi-chemical equation of state based on energy and density fluctuations in the small system grand canonical ensemble
• Abstracts: Pattern formation during polymerization of acrylamide in the presence of sulfide ions. New platform for testing candidate materials for organic field-effect transistors

This website is not affiliated with document authors or copyright owners. This page is provided for informational purposes only. Unintentional errors are possible.