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Determination of the enthalpy of solute-solvent interaction from the enthalpy of solution: Aqueous solutions of erythritol and L-threitol

Article Abstract:

The enthalpy of the solute-solvent interaction of erythritol and L-threitol in aqueous solution is determined from the values obtained for the enthalpy of solvation. The thermodynamic quantity involved in the enthalpy of the solute-solvent interaction helps in understanding the complexity of the tetritols aqueous solutions and the value obtained for the enthalpy of the solute-solvent interaction of erythritol is lower than that of L-threitol.

Author: Jesus, A.J. Lopes, Redinha, J.S., Tome, Luciana I.N., Eusebio, M. Ermelinda S.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Solvation, Aqueous solution reactions

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Determination of the enthalpy of solute-solvent interaction from the enthalpy of solution: Aqueous solutions of erythritol and L-threitolz

Article Abstract:

The enthalpy of the solute-solvent interaction of erythritol and L-threitol in aqueous solution is determined from the values obtained for the enthalpy of solvation. The thermodynamic quantity involved in the enthalpy of the solute-solvent interaction helps in understanding the complexity of the tetritols aqueous solutions and the value obtained for the enthalpy of the solute-solvent interaction of erythritol is lower than that of L-d

Author: Jesus, A.J. Lopes, Redinha, J.S., Tome, Luciana I.N., Eusebio, M. Ermelinda S.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Thermal properties, Structure, Chemical properties, Diastereomers, Hydration (Chemistry)

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Enthalpy of sublimation in the study of the solid state of organic compounds. Application to erythritol and threitol

Article Abstract:

The enthalpies of sublimation of erythritol and L-threitol are determined by calorimetry. The results show that the most important contribution to the differences observed in the enthalpy of sublimation are the differences in the enthalpy of conformational change rather than different intermolecular forces exhibited in the solid phase.

Author: Jesus, A.J. Lopes, Tome, I.N., Eusebio, Ermelinda, Redinha, J.S.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
Intermolecular forces, Sublimation (Physics)

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Subjects list: Research, Analysis, Enthalpy
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