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Chemicals, plastics and rubber industries

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Dispersion stability of colloids in sub- and supercritical water

Article Abstract:

The stability behavior of standard colloidal particles including metal, polymer and inorganic materials in sub- and supercritical water, are investigated. The surface charge density and Stern potential are found to change with respect to temperature due to the readjustment of the ion concentration in the diffuse layer through the enhanced ion product and reduced dielectric constant of water.

Author: Ghosh, Swapan K., Tsujii, Kaoru, Deguchi, Shigeru, Alargova, Rossitza G.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Electric properties, Light scattering, Mechanical properties, Dielectric measurements, Dielectric measurement

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Linking phase behavior and reversible colloidal aggregation at low concentrations: Simulations and stochastic mean field theory

Article Abstract:

The computer simulations and a theoretical model were used to examine the link between the kinetics of clustering and the phase behavior of dilute colloids with short range attractions of moderate strength. The weak attractions are found to be associated with a gas phase of small clusters, intermediate with liquid-gas separation and strong attractions with fractal unbreakable clusters.

Author: Puertas, Antonio M., Odriozola, Gerardo
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
Science & research, Research, Clusters (Chemistry), Chemical properties, Matter, Kinetic theory of, Kinetic theory, Report

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Free volumes and the anomalous self-diffusivity of attractive colloids

Article Abstract:

A conceptual revision to the traditional free volume perspective is proposed that takes into account both the size distribution and the characteristic persistence time of the free volumes. The results have shown that it can quantitatively captures the disparate behaviors of a model fluid with short-range attractions and its hard-sphere reference fluid.

Author: Truskett, Thomas M., Krekelberg, William P., Ganesan, Venkat
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Molecular dynamics, Thermodynamics, Properties

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Subjects list: Analysis, Colloids, Structure
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