Dissociation of water at the MgO(100)-water interface: comparison of theory with experiment

Article Abstract:

A study was conducted to analyze the dissociative chemisorption of water at the MgO(100)-water interfaces. Metastable impact electron spectroscopy was carried out to image the density of occupied states on the MgO(100)/Mo(100) surface. The CECILIA computation technique was utilized to determine the geometry and energetics of states for interfacial species. Experimental results indicated that the stabilization of charged OH- and H+ interface adsorbates correlate with the polarization of the surrounding solvent.

Analysis, Water, Water analysis, Magnesium, Magnesium (Metal)

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On the parallel mechanism of the dissociation of energy-selected P(CH3)3(super +) ions

Article Abstract:

Energy selected trimethyl phosphine ions are prepared by threshold photoelectron photoion coincidence (TPEPICO) spectroscopy. TPEPICO breakdown diagram of trimethyl phosphine, the time-of-flight distribution of the ions formed at photon energies between 10.53 and 12.73 eV, and numerous quantum calculations are described.

Science & research, Industrial Gas Manufacturing, Industrial gases, Phosphine, Usage, Photoelectron spectroscopy, Chemical properties

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