Effect of lithium chloride on the palisade layer of the Triton-X-100 micelle: Two sites for lithium ions as revealed by solvation and rotational dynamics studies

Article Abstract:

Dynamics strokes' shift measurements using coumarin 153 as the fluorescence probe is carried out to explore the effect of added electrolyte, lithium chloride on solvation dynamics in the Triton-X-100(TX-100) micelle and thus to understand the changes in micellar Palisade layer, especially the entrapped water structures in the Palisade layer. Solvation dynamics in the TX-100 micellar layer shows faster solvation with salt concentration up to about 1.5 M.

Lithium Compounds, Lithium Chloride, Chlorides, Dichloropropane

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Compartmentalization of reactants in different regions of sodium 1,4-bis(2-ethylhexyl)sulfosuccinate/heptane/water reverse micelles and its influence on bimolecular electron-transfer kinetics

Article Abstract:

The studies about the photoinduced electron-transfer (ET) reaction between some coumarin derivatives and amines such as aniline (AN) and N,N-dimethylaniline (DMAN) at different water/sodium 1,4-bis(2-ethylhexyl)sulfosuccinate (AOT) values which could make the systems more conducive for the observation of the Marcus inverted region is reported.

All Other Basic Organic Chemical Manufacturing, Industrial organic chemicals, not elsewhere classified, Nitrogen Compounds, Coumarin, Analysis, Electron transport, Coumarins, Amines

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Role of micellar size and hydration on solvation dynamics: A temperature dependent study in triton-X-100 and Brij-35 micelles

Article Abstract:

The temperature effect on solvation dynamics is investigated in two neutral micelles, namely, Triton X-100 and Brij-35 using dynamic fluorescence Stokes' shift method. The study is done to explore the role of micellar size and hydration on the solvation process.

Chemistry, Physical and theoretical, Physical chemistry

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