Pump-probe spectroscopy of the hydrated electron in reverse micelles

Article Abstract:

Ultrafast spectroscopy was used to investigate the excited state dynamics and photochemistry of the hydrated electron in the water pool of a reverse micelle (RM) comprised of water and the surfactant, AOT, dissolved in an isooctane solution. The isooctane-solvated electrons were observed to rapidly attach to the RM and relax in the water pool within 1 ps.

Micelles, Hydrates, Chemical properties

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Femtosecond spectroscopy of heterogeneous electron transfer: Extraction of excited-state population dynamics from pump-probe signals

Article Abstract:

A study is done on numerical calculations of pump-probe signals corresponding to excited-state adsorption of the molecular state. The study shows that information on the modulation of population transfer due to vibrational coherences can be deduced from the pump-probe signals.

Analysis, Electron transport

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