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Chemicals, plastics and rubber industries

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Fluorescence probing of temperature-dependent dynamics and friction in ionic liquid local environments

Article Abstract:

The solvatochromic fluorescence probe coumarin 153 (C153) is used to study the temperature dependence of the solvation dynamics and fluorescence depolarization dynamics in the ionic liquids. The C153 fluorescence anisotropy has shown very long time scale orientational relaxation time constants dynamics in the order of 100 ns.

Author: Wishart, James F., Funston, Alison M., Castner, Edward W., Jr., Fadeeva, Tatiana A.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
All Other Basic Organic Chemical Manufacturing, Coumarin, Solvation, Coumarins, Ionic solutions, Chemical properties

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Vapor-liquid equilibrium of ethanol by molecular dynamics simulation and Voronoi tessellation

Article Abstract:

Voronoi tessellations (VT) in two-phase molecular dynamics simulations are used for determining the coexisting densities and vapor-liquid equilibrium (VLE) of a polyatomic fluid, namely ethanol. The pair correlation function has shown significant hydrogen bonding in the liquid and vapor phase.

Author: Keffer, David J., Steele, William V., Fern, Jared T.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
Ethanol, Ethyl Alcohol Manufacturing, Observations, Electric properties, Alcohol, Molecular dynamics, Hydrogen bonding, Hydrogen bonds, Vapor-liquid equilibrium, Alcohol, Denatured, Vapour-liquid equilibrium, Tessellations (Mathematics)

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Subjects list: Analysis
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