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Functionalization and extraction of large fullerenes and carbon-coated metal formed during the synthesis of single wall carbon nanotubes by laser oven, direct current arc, and high-pressure carbon monoxide production methods

Article Abstract:

A method to functionalize the large fullereness by alkyl radicals and to affect a separation from the single-wall carbon nanotube (SWNT) by extraction of the soluble fullerene derivatives into chloroform is reported. It is found that small amount of carbon-coated metal is also extracted along with the large fullerenes.

Author: Smalley, Richard E., Sadana, Anil K., Billups, W. E., Hauge, Robert H., Brinson, Bruce, Liang, Feng, Arepalli, Sivaram, Farhat, Samir
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
Science & research, Research, Chemistry, Physical and theoretical, Physical chemistry, Carbon compounds, Fullerenes

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Cutting of single-walled carbon nanotubes by ozonolysis

Article Abstract:

A new cutting method for single walled carbon nanotubes (SWNT) using perfluoropolyether as reactant medium is described. This method uses extensive ozonolysis at room temperature and SWNT was found to be extensively cut after an ozone treatment with a yield of ~80% of the original carbon.

Author: Smalley, Richard E., Hauge, Robert H., Zheyi Chen, Ziegler, Kirk J., Shaver, Jonah
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
All Other Basic Organic Chemical Manufacturing, Industrial Organic Chemicals, Polyethers, Glycol ethers

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Subjects list: Chemical properties, Nanotubes
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