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Electrodesorption kinetics and molecular interactions in well-ordered thiol adlayers on Au(111)

Article Abstract:

The electrodesorption of square root of 3 * square root of 3 R30 degrees and c(4 * 2) lattices for S and thiols involves nucleation and growth of holes. The S-Au(111) bond for adsorbed thiols in the square root of 3 * square root of 3 R30 degrees adlayer is less ionic than that found for S in the same lattice. The energy difference introduced by this 'extra' ionic character is approximately 19 kJ mol(super -1).

Author: Andreasen, G., Vericat, C., Vela, M.E., Salavrezza, R. C., Martin, H., Creus, A. Hernandez
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
All Other Basic Organic Chemical Manufacturing, All Other Basic Inorganic Chemical Manufacturing, Industrial Organic Chemicals, Industrial inorganic chemicals, not elsewhere classified, Mercaptans, Gold Compounds, Nucleation, Nucleation (Chemistry), Thiols

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Influence of the nanostructure of palladium mesoparticles on the kinetics of molecular oxygen electroreduction

Article Abstract:

The effect of the nanostructure of electrodeposited palladium mesoparticles on the oxygen electroreduction reaction (oerr) in acid media is studied by electrochemical techniques combined with scanning tunneling microscopy, tapping-mode atomic force microscopy, and scanning electron microscopy. Palladium mesoparticles supported on highly oriented pyrolytic graphite exhibit a remarkable electrocatalytic enhancement.

Author: Salvarezza, R. C., Creus, A. Hernandez, Gonzalez, S., Gimeno, Y., Diaz, P., Vazquez, L., Arvia A. J.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Palladium, Usage, Atomic force microscopy

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Subjects list: Research, Electric properties, Chemistry, Physical and theoretical, Physical chemistry
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