Light energy conversion using mixed molecular nanoclusters. Porphyrin and C60 cluster films for efficient photocurrent generation

Article Abstract:

A new approach of preparing composite clusters of porphyrin and fullerene in acetonitrile/toluene mixed solvents and assembling them on a nanostructured SnO2 electrode, using an electrophoretic deposition technique, is reported. The composite clusters of porphyrin and fullerene absorb light over the entire spectrum of visible light.

Usage, Tin compounds, Electrophoretic deposition

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Electrostatic assemblies of fullerene-porphyrin hybrids: toward long-lived charge separation

Article Abstract:

The Coulomb complex formation of a dendrite fullerene oligocarboxylate (1 to the power -8) and an octapyridinium zinc porphyrin salt (ZnP to the power 8+) is studied. The molecular dynamic simulations provide an understanding of the supramolecular structure of the fullerene-porphyrin hybrid, ZnP to the power 8+/1to the power 8-.

Influence, Molecules, Fullerenes

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Enhanced aggregation behavior of antimony(V) porphyrins in polyfluorinated surfactant/clay hybrid microenvironment

Article Abstract:

The photophysics and potential photochemistry of polyfluorinated microcavities is highlighted. The application of cation-exchangeable type clays in the intercalation of metalloporphyrin molecules is explained.

Chemical reactions, Photochemistry

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