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Macroscopic diffusion and low-frequency vibrations of sodium on Pt(111) investigated with helium atom scattering

Article Abstract:

Quasielastic helium atom scattering (QHAS) techniques are used to study the diffusion and lateral vibrations of a low coverage Theta(sub Na)=0.043 of sodium atoms on a Pt(111) surface. On account of the competition between on-top and hollow site adsorption on the hexagonal Pt(111) surface, this system provides a comparison with the diffusion of Na/Cu(001).

Author: Janesko, Benjamin G., Walker, Gilbert C., Jachmann, Rabecca C., Beebe, Thomas P., Jr., Graham, Andrew P., Toennies, J. Peter
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
Observations, Adsorption

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Electron attachment to ethyl adsorbed on platinum

Article Abstract:

Ab initio electron structure calculations are performed on ethyl adsorbed on Pt(100) to investigate whether photoexcitation and the resulting electron attachment to ethyl would induce dissociation by H transfer to the surface. Using an embedded cluster description of the adsorbate-metal system, calculations are carried.

Author: Hammer, B., Norskov, J.K, Watwe, R., Dumesic, J., Stumpf, R., Whitten, J.L., Wagner, F, Scheffler, M.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
Electrons, Structure

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Subjects list: Research, Platinum, Chemistry, Physical and theoretical, Physical chemistry, Atomic properties
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