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Chemicals, plastics and rubber industries

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Optimal separation sequence for three-component mixtures

Article Abstract:

An analysis is done to determine the method to select the most effective separation sequence for a three-component mixture in a two binary separation stages system. The rate of flow of input mixture cannot be higher than the bound (maximum possible rate of heat-driven separation) for a heat-driven two-stage separation system.

Author: Kazakov, Vladimir, Tsirlin, Anatoly M., Romanova, T.S.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
Science & research, Research, Gibbs' free energy, Solution (Chemistry), Solutions (Chemistry), Binary system (Mathematics)

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A fluctuation theory analysis of the salting-out effect

Article Abstract:

The analysis of the salting-out, or Sechenw, effect is given in terms of Kirkwood-Buff, or fluctuation, integrals. The simplifications arise when the solute that is being salted out is sparingly soluble and the theory can be used to compute one of the Kirkwood-Buff integrals, which is otherwise difficult to obtain.

Author: Mazo, Robert M.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
United States, Fluctuations (Physics)

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Subjects list: Analysis
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