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Chemicals, plastics and rubber industries

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Photophysical properties and photocatalytic activities of bismuth molybdates under visible light irradiation

Article Abstract:

The photophysical and photocatalytic properties of oxides consisting of a [Bi.sup.3+] ion with 6[s.sup.2] configuration and [Mo.sup.6+] ion with 4[d.sup.0] configuration were studied to develop photocatalysts with visible light response. The photocatalytic activity of the Aurivilllius structure B[i.sub.2]Mo[O.sub.6] prepared by the reflux method was dependent on the annealing temperature after the preparation.

Author: Kudo, Akihiko, Kato, Hideki, Kobayashi, Hisayoshi, Shimodaira, Yoshiki
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Bismuth, Irradiation, Thermal properties, Annealing, Irradiation (Radiation exposure)

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Photocatalytic H2 evolution under visible-light irradiation over band-structure-controlled (CuIn)(sub x)Zn[sub (2(1-x))]S2 solid solutions

Article Abstract:

A study carried out on the (CuIn)(sub x)Zn[sub (2(1-x))]S2 solid solutions between a ZnS photocatalyst with a wide band gap and CuInS2 with a narrow band gap is presented. The results show photocatalytic activities for hydrogen evolution from aqueous solution containing sacrificial reagents SO(sub 3)(super 2-) and S(super 2-) under visible-light irradiation (lambda greater than or equal to 420 nm).

Author: Kudo, Akihiko, Kato, Hideki, Kobayashi, Hisayoshi, Tsuji, Issei
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
Industrial Gas Manufacturing, Industrial gases, Hydrogen, Analytical Laboratory Instrument Manufacturing, Analytical instruments, Scanning Microscopy, Spectra

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Subjects list: Analysis, Optical properties, Properties
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