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Chemicals, plastics and rubber industries

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Equation of state for the phase coexistence region of insoluble monolayers under consideration of the entropy nonideality

Article Abstract:

The generalization of the equation of state for the monolayer with a fluid/condensed phase transition derived in the framework of a quasichemical approach is reported. The calculated results from equations provide insight into entropy nonideality of mixing of the monomers and clusters of amphiphilic molecules.

Author: Vollhardt, D., Fainerman, V.B.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2008
Analysis, Monomolecular films, Thermal properties, Monomers, Entropy (Physics), Entropy (Thermodynamics), Equations of state

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Dynamics and equilibrium of the penetration of soluble cetyltrimethylammonium bromide into Langmuir monolayer of arachidic acid under different pH conditions

Article Abstract:

Experimental studies of the dynamics and equilibrium of the penetration of the soluble cationic surfactant cetyltrimethylammonium bromide (CTAB) into arachidic acid monolayers are reported. A new theoretical model is proposed involving the enthalpic nonideality of the mixed monolayer.

Author: Vollhardt, D., Fainerman, V.B., Roth, A., Fricke, M., Volkmer, D.
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2004
Science & research, Nitrogenous Fertilizer Manufacturing, Nitrogenous fertilizers, Ammonia, Research, Dynamics, Dynamics (Mechanics), Bromides, Bromides (Chemistry)

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