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Chemicals, plastics and rubber industries

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Appearance of an oscillation through the autocatalytic mechanism by control of the atomic-level structure of electrode surfaces in electrochemical H2O2 reduction at Pt electrodes

Article Abstract:

A new study investigates the influence of the atomic-level structure of electrode surfaces on electrochemical oscillations in an H2O2-acid-Pt electrode system.

Author: Nakanishi, Shuji, Mukouyama, Yoshiharu, Karasumi, Kouhei, Imanishi, Akihito, Furuya, Nagakazu, Nakato, Yoshihiro
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Chemistry, Physical and theoretical, Physical chemistry

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Roles of local deviations and fluctuations of the helmholtz-layer potential in transitions from stationary to oscillatory currents in an "H (sub 2) O (sub 2)- acid-Pt" electrochemical system

Article Abstract:

The mechanism of transitions from stationary to oscillatory currents is studied for hydrogen oxide reduction at platinum electrodes in acidic solutions. The transitions were observed in current versus time curves after the electrode potential is stepped from the rest potential to a potential where an oscillation appeared.

Author: Mukouyama, Yoshiharu, Nakato, Yoshihiro, Catherine Henry de Villeneuve, Nishimura, Takashi, Nakanashi, Shuji
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2000
Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), Oxygen, Industrial Gas Manufacturing, Platinum, Industrial gases, Hydrogen, Electric properties

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Catalytic effect of adsorbed iodine atoms on hydrogen peroxide reduction at single-crystal Pt electrodes, causing enhanced current oscillations

Article Abstract:

The oscillation E is enhanced much by the presence of adsorbed iodine atoms. The adsorbed iodine atoms have catalytic effect on the dissociative adsorption of H2O2, which leads to the enhancement of oscillation E.

Author: Nakanishi, Shuji, Mukouyama, Yoshiharu, Nakato, Yoshihiro
Publisher: American Chemical Society
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
All Other Basic Inorganic Chemical Manufacturing, Industrial inorganic chemicals, not elsewhere classified, Hydrogen Peroxide, Iodine & Compounds, Iodine, Adsorption, Oscillation, Oscillations, Chemical properties

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Subjects list: Research, Electrochemistry
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