Thermodynamics of ion transfer across the liquid/liquid interface at a solid electrode shielded with a thin layer of organic solvent

Article Abstract:

Thermodynamics of ion transfer across the liquid/liquid interface at a solid electrode shielded with a thin layer of water-immiscible organic solvent is studied. A commercial hydrophobic carbon filament material (LSG) as an electrode support, and a specially synthesized water-insoluble, redox, electroactive polymer (polyphenotiazine, PPTA) as a mediator, is used to make the hydrophobic-shielded electrode.

Electric properties, Thermodynamics, Electrodes

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Electrostatic contribution to the stability and the synergism of ionic/nonionic mixed micelles in salt solutions

Article Abstract:

A phenomenological procedure to analyze the stability and the synergism of ionic/nonionic mixed micelles in salt solutions under few assumptions is presented. In addition, several popular approaches in this area are also discussed.

Electrostatics, Micelles, Chemical reactions

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