Carbocationic alkene polymerizations initiated by organotransition metal complexes: an alternative, unusual role for soluble Ziegler-Natta catalysts

Article Abstract:

The author reviews the publications on the alkenes which may be polymerized into homopolymers via free-radical polymerization. The topics of interest include the carbocationic initiation of alkene polymerization and the utilization of the organotransition metal complexes which are Ziegler-Natta catalysts as carbocationic initiators.

Canada, Carbon, Cations, Solution (Chemistry), Solutions (Chemistry)

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Copolymerization of polar monomers with olefins using transition-metal complexes

Article Abstract:

The authors review the publications on the olefin polymerization system evolution. The topics of interest include homopolymerization of (meth)acrylates, direct functional monomer copolymerization with group IV catalysts and protecting group chemistry.

United States, Monomers

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