Rhodium-catalyzed carbon-carbon bond forming reactions of organometallic compounds

Article Abstract:

The authors review the publications on transition metal catalysts. The topics of interest include the investigation of catalytic possibilities, catalytic processes, and the use of transition metal catalysts in carbon-carbon bond formation.

Canada, Primary nonferrous metals, not elsewhere classified, Primary Smelting and Refining of Nonferrous Metal (except Copper and Aluminum), All Other Basic Organic Chemical Manufacturing, All Other Miscellaneous Chemical Product and Preparation Manufacturing, Catalysts, Industrial Organic Chemicals, Chemical preparations, not elsewhere classified, Rhodium, Organometals, Analysis, Composition, Precious metal products, Chemical research, Chemical reactions, Chemical bonds, Organometallic compounds, Properties, Chemical properties

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Transition metal-mediated cycloaddition reactions

Article Abstract:

Cycloaddition reactions are synthetic methods that are rapidly gaining applicability in organic chemistry. These reactions require the presence of heat, light, Lewis acids, high pressure and polarized functional groups in the substrate to aid transformation and achieve good yields of cycloadducts. Metal catalysts are compounds increasingly being used to promote complexation and achieve increased reactivity. An attractive feature of this strategy is enantioselective transformations upon the addition of chiral ligands. Some examples of transition metal-mediated cycloaddition reactions are presented. The discussion focuses on the sizes of rings formed rather than on the properties of reaction products.

Research, Usage, Organic compounds, Metal catalysts, Organic compound synthesis, Ring formation (Chemistry), Cyclization (Chemistry)

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