Design, chirality, and flexibility in nanoporous molecule-based materials

Article Abstract:

Scientific and technological interest in porous materials with molecule-sized channels and cavities has led to an intense search for controlled chemical routes to systems with specific properties. The way in which the assembly of open-framework structures based on molecules is directed and how the response of nanoporous examples of such materials to guests differs from classical rigid porous systems is investigated.

Chirality, Chemical properties

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Confinement of metal complexes within porous hosts: Development of functional materials for gas binding and catalysis

Article Abstract:

Porous functional materials that exhibit function in gas binding/release and catalysis are developed by using template copolymerization. The organizations of ligands within the immobilized sites are solvent-dependent, conveying the importance of the synthetic conditions on the immobilized site formation during the copolymerization process.

Petroleum Refineries, Petroleum refining, Kansas, Polymerization, Analysis, Ligands, Ligands (Chemistry), Properties, Structure

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Orientational dynamics of liquids confined in nanoporous sol-gel glasses studied by optical Kerr effect spectroscopy

Article Abstract:

Nanoporous sol-gel glasses model system is used to study the effects of confinement on the orientational dynamics of weakly wetting, strongly wetting, and networked liquids. Influence of factors such as pore size, molecular shape, and surface chemistry along with the results obtained from optical Kerr effect spectroscopy are accounted.

Usage, Spectrum analysis, Spectroscopy

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