Phosphoryl transfer enzymes and hypervalent phosphorus chemist
Article Abstract:
The coordination tendencies of phosphorus to form a hexacoordinated state from a pentacoordinated state, which might assist in describing the mechanistic action of phosphoryl transfer enzymes, are delineated. It is suggested that the donor action should play a role in determining active site interactions in phosphoryl transfer enzyme mechanisms.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2004
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New features in pentacoordinate phosphorus chemistry
Article Abstract:
The new developments in the phosphorous centered reactions are described where a pentacoordiante transition state species or an intermediate or a stable molecule is encountered. Apicophilicity, fluxional behavior, bond parameters, tetra versus pentacoordination and P-O or P-N bond distances in PX4N and PO4N systems are also discussed.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2006
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Asymmetric hydrogenation using monodentate phosphoramidite ligands
Article Abstract:
Monodentate phosphoramidites are a highly versatile class of ligands, which are used for asymmetric hydrogenation. The ligands are highly modular and easy to synthesize enabling their robotic parallel synthesis.
Publication Name: Accounts of Chemical Research
Subject: Science and technology
ISSN: 0001-4842
Year: 2007
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