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Physicochemical transport processes affecting the removal of residual DNAPL by nonionic surfactant solutions

Article Abstract:

Dense nonaqueous phase liquids (DNAPLs) prevent remediation of contaminated aquifers by preventing the solubilization and mobilization of residual NAPL. A new method that increases the efficiency of NAPL removal and surfactant recovery involves the use of nonionic surfactants such as Triton X-100. The technology promotes the removal of residual NAPL by improving macroemulsion transport. Mathematic models describing the technology are included.

Author: Miller, Cass T., Okuda, Itaru, Gleyzer, Simon N., McBride, John F.
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1996
Methods, Management, Usage, Bioremediation, Surface active agents

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Evaluation of thermal effects on the dissolution of a nonaqueous phase liquid in porous media

Article Abstract:

Hot water flooding was not effective in remediating a porous medium containing the nonaqueous phase liquid (NAPL) tetrachlorethylene. The method, used at different temperatures, was found to have only a 7% effect on interfacial tension at the NAPL interface and thus a minor effect for mass transfer. However, hot water flooding could be useful if temperature increases have a significant effect on a contaminant's aqueous phase solubility.

Author: Miller, Cass T., Imhoff, Paul T., Frizzell, Angela
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1997
Research and Development in the Physical, Engineering, and Life Sciences, Water Pollution Control R&D, Organic water pollutants, Organic water pollution, Water pollution research, Decontamination (from gases, chemicals, etc.), Decontamination

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Cosolvent-enhanced remediation of residual dense nonaqueous phase liquids: experimental investigation

Article Abstract:

The effectiveness of cosolvents in removing dense nonaqueous phase liquids (DNAPLs) at residual saturation within porous media is evaluated. The results showed that methanol flushing caused the mobilization, non-equilibrium dissolution and flow bypassing of tetrachloroethylene. Small-scale heterogeneities can lead to high residual DNAPL saturations which lend themselves easily to mobilization.

Author: Miller, Cass T., Okuda, Itaru, Imhoff, Paul T., Gleyzer, Simon N., McBride, John F., Vancho, Laura A.
Publisher: American Chemical Society
Publication Name: Environmental Science & Technology
Subject: Science and technology
ISSN: 0013-936X
Year: 1995
Solvents

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Subjects list: Aquifers, Research
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