An in situ energy-dispersive x-ray diffraction study of the hydrothermal crystallization of zeolite A. 1. Influence of reaction conditions and transformation into sodalite
Article Abstract:
The hydrothermal crystallization of sodium zeolite A from amorphous aluminosilsicate gels at 80-120 degree Celsius is investigated via a time-resolved in situ energy-dispersive X-ray diffraction. The course of crystallization reaction is analyzed by quantifying the Avarami-Erofe'ev nucleation growth curves, which indicate that choice of silica starting material affect the course of reaction, and the concentration of NaOH and temperature determine the crystallization behavior.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
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An in situ energy-dispersive x-ray diffraction study of the hydrothermal crystallization of zeolite A. 1. Influence of reaction conditions and transformation into sodalite
Article Abstract:
The hydrothermal crystallization of sodium zeolite A from amorphous aluminosilsicate gels at 80-120 degree Celsius is investigated via a time-resolved in situ energy-dispersive X-ray diffraction. The course of crystallization reaction is analyzed by quantifying the Avarami-Erofe'ev nucleation growth curves, which indicate that choice of silica starting material affect the course of reaction, and the concentration of NaOH and temperature determine the crystallization behavior.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
User Contributions:
Comment about this article or add new information about this topic:
An in situ energy-dispersive X-ray diffraction study of the hydrothermal crystallization of zeolite A. 2. Effect of deuteration of crystallization kinetics
Article Abstract:
The crystallization of zeolite A from amorphous aluminosilicate gels at 10 degrees Celsius is examined by energy-dispersive X-ray diffraction. The effect of deuteration of reagents on the kinetics of a zeolite crystallization is described and the finings are discussed in relation to previously postulated zeolite crystallization mechanisms.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
User Contributions:
Comment about this article or add new information about this topic:
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