Photo-electro-oxidation of alcohols on titanium dioxide thin film electrodes
Article Abstract:
The formation of -OH radicals during the oxidation process creates a potential impact on the charge transfer of methanol. Photoelectrochemical analysis conducted on titanium dioxide thin film electrodes revealed that the interaction of -OH with CH3OH tends to generate an increase in initial photocurrents, which in turn, expedites the rate of photo-electro-oxidation of methanol. The entire process may also be hastened through the integration of an electron into the current doubling band, eventually leading an increased photocurrent and more stable state values.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
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Anion-exchange equilibrium and phase segregation in hydrotalcite systems: Intercalation of hexacynoferrate (III) ions
Article Abstract:
A study of the intercalation of hexacyanoferrate (III) in chloride-hydrotalcite is presented as a function of the composition of the equilibrated aqueous phase, the relevant solution variable being the ratio [C(sub Fe(CN)6)(super 3-)](super 1/3)/C(sub cr). The isotherm concluded that the exchange is markedly nonideal and reveals the segregation of two solid phases of fixed compositions at [C(sub Fe(CN)6)(super 3-)](super 1/3)/C(sub cr) = 17.1 M(super -2/3).
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
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Anion-exchange equilibrium and phase segregation in hydrotalcite systems: Intercalation of hexacynoferrate (III) ions
Article Abstract:
A study of the intercalation of hexacyanoferrate (III) in chloride-hydrotalcite is presented as a function of the composition of the equilibrated aqueous phase, the relevant solution variable being the ratio [C(sub Fe(CN)6)(super 3-)](super 1/3)/C(sub cr). The isotherm concluded that the exchange is markedly nonideal and reveals the segregation of two solid phases of fixed compositions at [C(sub Fe(CN)6)(super 3-)](super 1/3)/C(sub cr) = 17.1 M(super -2/3).
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2005
User Contributions:
Comment about this article or add new information about this topic:
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