Comparisons of measured rate constants with spectroscopically determined electron-transfer parameters
Article Abstract:
A comparison of rate constants measured for an intervalence (IV) compounds with electron-transfer parameters obtained from its optical absorption spectrum is done using resonance Raman analysis. It is suggested that the Zhu-Nakamura preexponential factor provides good consistency for the ESR rate constants using a value, averaged single-mode which closer to those predicted from the resonance Raman spectroscopic data but need slightly higher electronic coupling than [V.sub.Hush].
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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Extracting biochemical parameters for cellular modeling: A mean-field approach
Article Abstract:
A method of filling in missing parameters using an approach conceptually analogous to mean-field approaches in statistical mechanics is presented. This methodology is applied to account for the effect of the presence of the Escherichia coli genome on the availability of key enzymes involved in gene expression, yielding the number of free enzymes as a function of cellular growth rate.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2006
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