Electronic structure of a chemisorbed layer at electrochemical interface: copper layer on gold electrode
Article Abstract:
A model Hamiltonian is constructed to describe an electrochemisorbed layer. The proposed model, which is a generalized version of the Anderson-Newns Hamiltonian, can be used for a random adsorbate layer with arbitrary coverage and the ensuing two-dimensional band formation by metallic adsorbates in the monolayer regime. This model Hamiltonian is tested on the electrosorption of copper ion on gold electrode and used to determine coverage dependence of adsorbate charge, binding energy, adsorbate density of states.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
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Electrochemically induced dynamics of a benzylic amide [2]catanane
Article Abstract:
An investigation into the electrochemistry of benzylic amide[2]catenane is presented together with a comparison with its topologically trivial components.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 1999
User Contributions:
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