Direct determination of equilibrium thermodynamics and kinetic parameters from isothermal heat conduction microcalorimetry
Article Abstract:
Calorimetry is recognized as noninvasive, non-destructive method for the determination of both the thermodynamic and the kinetic parameters associated with chemical reactions. The aqueous-solution-phase, imidazole-catalyzed hydrolysis of triacetin is considered as a test reaction for isothermal heat conduction microcalorimeters used to evaluate both thermodynamic and kinetic parameters.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
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Polyelectrolytic amphiphilic model neworks in water: a molecular thermodynamic theory for their microphase separation
Article Abstract:
The study was conducted on the aqueous aggregation behavior of networks comprising hydrophilic ionic blocks and hydrophobic nonionic blocks by formulating a molecular thermodynamic theory. The results show the unimer-to-miscelle transition accompanied by a discontinuous change in the degree of swelling of the networks.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2001
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Application of chemometric analysis to complexity in isothermal calorimetric data
Article Abstract:
The potential application of chemometric analysis for interpretation of complex isothermal calorimetric data is discussed.
Publication Name: Journal of Physical Chemistry B
Subject: Chemicals, plastics and rubber industries
ISSN: 1520-6106
Year: 2007
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